引导的状语表示伴随，而状语从句主要有时间状语 地点状语 条件状语 原因状语。
伴随状语从句:用with引导的话,表示在进行一项动作的同时在进行另外一个动作,后面用名词+介词短语,或者直接用动词ing形式.
如:The teacher came into the classroom,with books under her arm.She came here,with running.
复合结构就是用一些介词,副词来引导的句子,比较起简单句说有点复杂而已.
如 she not only passes the exam but also get a high mark.
用with的话,
如 with his help,she get a high mark.其中with his help不过是一个状语成分,作条件讲。
扩展资料：
一、从句作状语
When she was 12 years old, she began to live in Dalian.
她12岁的那一年开始居住于大连。
If I am not busy tomorrow, I will play football with you.
如果我明天不忙，我就会陪你踢足球。
二、连词+过去分词
He won't go there with us unless (he is) invited.
除非受到邀请,否则他不会和我们一道去那里。
三、with 复合结构，在句中表状态或说明背景情况 该结构常做伴随、方式、原因、条件等状语。
例句：1、With machinery to do all the work, they will soon have got in the crops.
由于所有的工作都是由机器进行，他们将很快收完庄稼。（原因状语）
2、The boy always sleeps with his head on the arm.
这个孩子总是头枕着胳膊睡觉。（伴随状语）
3、The soldier had him stand with his back to his father.
士兵要他背对着他父亲站着。（方式状语）
4、With spring coming on, trees turn green.
春天到了，树变绿了。（时间状语）
四、with 复合结构可以作定语
例句：Anyone with its eyes in his head can see it’s exactly like a rope.
任何一个头上长着眼睛的人都能看出它完全像一条绳子。
参考资料来源：百度百科：状语
参考资料来源：百度百科：状语从句
参考资料来源：百度百科：With复合结构